联合国关于危险货物运输的建议书－试验和标准手册（2009年－第五修订版）
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Recornmendations on the
TRANSPORT OF DANGEROUS GOODS
Manual of Tests and Criteria
FOREWORD
The "Recommendations on the Transport of Dangerous Goods, Manual of Tests and Criteria" supplement the "Recommendations on the Transport of Dangerous Goods, Model Regulations" and the "Globally Harmonized System of Classification and Labelling of Chemicals (GHS)". They contain criteria, test methods and procedures to be used for the classification of dangerous goods according to the provisions of Parts 2 and 3 0f the Model Regulations, as well as of chemicals presenting physical hazards according to the GHS.
Originally developed by the Economic and Social Council's Committee of Experts on the Transport of Dangerous Goods, which adopted a first version in 1984, the Manual of Tests and Criteria has been regularly updated and amended. Presently, the updating is done under the auspices of the Committee of Experts on the Transport of Dangerous Goods and on the Globally Harmonized System of Classification and Labelling of Chemicals, which replaced the original committee in 2001.
This fifth revised edition includes all the amendments to the fourth revised edition adopted by the Committee at its second and third sessions in 2004 and 2006 (published under the symbols ST/SG/AC.10/11/Rev.4/Amend.l and ST/SG/AC.10/1I/Rev.4/Amend.2) and those adopted at its fourth session in 2008 (ST/SG/AC.10/36/Add.2 and -/Corr.l).
Among the new amendments are revised provisions for the testing and classification of lithium metal and lithium ion batteries (Sub-section38.3), new test methods for transport equipment (Part IV), an additional test for assigning classification code l.4S to certain articles (Section 16, unconfined package test), a new test for determining whether pyrotechnic substances are to be considered as flash compositions for the purpose of classification (Appendix 7), as well as various other revised provisions.
GENERAL TABLE OF CONTENTS
1. GENERAL INTRODUCTION (lntroduction, Layout, Precedence of hazard characteristics, Safety, General conditions for testing, Recommended tests and Reporting)
PART Ⅰ: CLASSIFICATION PROCEDURES, TEST METHODS AND CRITERIA RELATING TO EXPLOSIVES OF CLASS 1
10. INTRODUCTION TO PART Ⅰ (Purpose, Scope, Acceptance procedure, Assignment procedure, Examples of test reports)
11. TEST SERIES l (To determine if a substance has explosive properties)
12. TEST SERIES 2 (To determine if a substance is too insensitive for inclusion in Class 1)
13. TEST SERIES 3 (To determine if a substance is thermally stable and not too dangerous for transport in the form in which it was tested)
14. TEST SERIES 4 (To determine if an article, packaged article or packaged.substance is too dangerous for transport)
15. TEST SERIES 5 (To determine if a substance may be assigned to Division 1.5)
16. TEST SERIES 6 (To assign a substance or article to Division 1.1, 1.2, 1.3 or 1.4 or exclude it from Class l)
17. TEST SERIES 7 (To determine if an article may be assigned to Division 1.6)
18. TEST SERIES 8 (To determine if an ammonium nitrate emulsion, suspension or gel, intermediate for blasting explosives (ANE), is insensitive enough for inclusion in Division 5.1, and to evaluate the suitability for transport in tanks)
PART Ⅱ: CLASSIFICATION PROCEDURES, TEST METHODS AND CRITERIA RELATING TO SELF-REACTIVE SUBSTANCES OF DI'VISION 4.1 AND ORGANIC PEROXIDES OF DMSION 5.2
20. INTRODUCTION TO PART Ⅱ (Purpose, Scope, Preliminary procedure, Classification procedures, Example of test report)
21. TEST SERIES A (To determine if there is propagation of detonation)
22. TEST SERIES B (To determine if there is detonation in the package)
23. TEST SERIES C (To determine if there is propagation of deflagration)
24. TEST SERIES D (To determine if there is rapid deflagration in the package)
25. TEST SERIES E (To determine the effect of heating under confinement)
26. TEST SERIES F (To determine the explosive power)
27. TEST SERIES G (To determine if there is thermal explosion in the package)
28. TEST SERIES H (To determine the self-accelerating decomposition temperature)
PART Ⅲ: CLASSIFICATION PROCEDURES, TEST METHODS AND CRITERIA RELATING TO CLASS 2, CLASS 3, CLASS 4, DIVISION 5.1, CLASS 8 AND CLASS 9
30. INTRODUCTION TO PART Ⅲ (Purpose, Scope)
31. CLASSIFICATION PROCEDURES, TEST METHODS AND CRITERIA RELATING TO FLAMMABLE AEROSOLS OF CLASS 2
32. CLASSIFICATION PROCEDURES, TEST METHODS AND CRITERIA RELATING TO LIQUID DESENSITIZED EXPLOSIVES AND FLAMMABLE LIQUIDS OF CLASS 3
33. CLASSIFICATION PROCEDURES, TEST METHODS AND CRITERIA RELATING TO CLASS 4
34. CLASSIFICATION PROCEDURES, TEST METHODS AND CRITERIA RELATING TO OXIDIZING SUBSTANCES OF DIVISION 5.1
35. Reservedfor classification procedures, test methods and criteria relating to Class 6
36. Reservedfor classification procedures, test methods and criteria relating to Class 7
37. CLASSIFICATION PROCEDURES, TEST METHODS AND CRITERIA RELATING TO SUBSTANCES OF CLASS 8
38. CLASSIFICATION PROCEDURES, TEST METHODS AND CRITERIA RELATING TO CLASS 9
PART Ⅳ: TEST METHODS CONCERNING TRANSPORT EQUIPMENT
40. INTRODUCTION TO PART Ⅳ (Purpose, Scope)
41. DYNAMIC LONGITUDINAL IMPACT TEST FOR PORTABLE TANKS AND MULTIPLE-ELEMENT GAS CONTAINERS (MEGCs)
APPENDICES
Appendix I SPECIFICATIONS OF STANDARD DETONATORS
Appendix 2 BRUCETON AND SAMPLE COMPARISON METHODS
Appendix 3 CAVITATION OF SAMPLES
Appendix 4 NATIONAL CONTACTS FOR TEST DETAILS
Appendix 5 EXAMPLE OF A TEST METHOD FOR VENT SIZING
Appendix 6 SCREENING PROCEDURES
Appendix 7 HSL FLASH COMPOSITION TEST
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